SHシリーズ
揮発性有機化合物③
Volatile Organic Compounds
1. dichlorodifl uoromethane | 2. chloromethane | 3. vinyl chloride | 4. bromomethane | 5. chloroethane |
6. trichlorofl uoromethane | 7. 1,1-dichloroethene | 8. carbon disulfi de | 9. 1,1,2-trichloro-1,2,2-trifl uoroethane | 10. methylene chloride |
11. acetone | 12. trans-1,2-dichloroethene | 13. methyl acetate | 14. methyl tert-butyl ether | 15. 1,1-dichloroethane |
16. cis-1,2-dichoroethane | 17. cyclohexane | 18. bromochloromethane (IS) | 19. chloroform | 20. carbon tetrachloride |
21. 1,1,1-trichloroethane | 22. Propachlor | 23. benzene | 24. Cycloate | 25. 1,2-dichloroethane |
26. methylcyclohexane | 27. trichloroethene | 28. 1,4-difl uorobenzene (IS) | 29. 1,2-dichloropropane | 30. bromodichloromethane |
31. cis-1,3-dichloropropene | 32. toluene d8 (SS) | 33. toluene | 34. tetrachloroethane | 35. 4-methyl-2-pentanone |
36. trans-1,3-dichloropropane | 37. 1,1,2-trichloroethane | 38. dibromochloromethane | 39. 1,2-dibromoethane | 40. 2-hexanone |
41. chlorobenzene d5 (IS) | 42. chlorobenzene | 43. ethylbenzene | 44. m-xylene | 45. p-xylene |
46. o-xylene | 47. styrene | 48. bromoform | 49. isopropylbenzene | 50. 4-bromofl uorobenzene (SS) |
51. 1,1,2,2-tetrachloroethane | 52. 1,3-dichlorobenzene | 53. 1,4-dichlorobenzene | 54. 1,2-dichlorobenzene | 55. 1,2-dibromo-3-chloropropane |
56. 1,2,4-trichlorobenzene |
Column | SH-VMS, 30 m, 0.25 mm ID, 1.40 μm (P/N: 227-36268-01) | Inj. | Split (split ratio: 35:1) |
---|---|---|---|
Purge and Trap | Trap:#10 (Tenax®/silica gel/carbon molecular sieve) | Inj. Temp | 200℃ |
Sample Temp:ambient | Carrier Gas | He, linear velocity 34 cm/sec., 40℃, constant flow | |
Purge:11 min @ 40 mL/min | Oven Temp | 40℃ (hold 4 min) to 90℃ @16 °C/min to 220℃ at 32℃/min (hold 5 min) | |
Desorb preheat:185℃ | Detector | MS | |
Desorb:0.5 min @ 190℃ | Transfer Line Temp: 150 °C | ||
Desorb flow rate:35.0 mL/mi | Scan Range: 35-300 amu. | ||
Bake:8 min @ 210℃ | Ionization: EI | ||
Interface:split injector | |||
Transfer Line Temp:150℃ |
【出典】株式会社島津製作所SHシリーズアプリデータ集 (株式会社島津ジーエルシー発行)